SYNTHESIS OF ADSORBENTS FOR OIL SPILL REMEDIATION (CLEANING OF OIL-SPILL CONTAMINATED SOIL) USING WASTE WATER SACHET(LDPE) AND SPENT ENGINE OIL

Student: Okechukwu Wisdom Joshua
Supervisor: Engr Chukwuka Henry Oyeoka
HOD: Dr Obumneme Emmanuel Ezeani
Department of Polymer and Textile Engineering
Engineering
Nnamdi Azikiwe University, Awka, Anambra State

Abstract

In this study, the conversation of waste water packaging material to oil absorbent for the remediation of oil spillage was investigated. Absorbent film was produced by melt- mixing the waste Plastic with solvent, introduction of various additives, followed by solvent extraction to generate pores. The solvents: Mineral oil and condemned oil were compared. Varying ratios of Low-density polyethylene (LDPE) to High density polyethylene (HDPE) from 1:1 to 1:4 were used. The Polymer solvent ratio was also varied from 10:90, 20:80 then 30:70. It was found that the LDPE and HDPE ratio 1:4 and the polymer to solvent ratio 10:90 gave the results. The temperature effect on the uptake capacity was also investigated. It was found that an increase in temperature improved the uptake capacity. Also, an isocyanate to polymer blend of 1:1 produced the best results. Absorbent with an uptake capacity of more than 100% its weight was achieved. The samples were characterized using SEM to examine the pore distribution. From the SEM results, it was confirmed that the use of isocyanate increased the porosity of the reusability and the recyclability of the absorbent and provide environmentally safe synthesis methods.

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